The members of the ORFEO-CINQA team have vide experience in the study of processes involving organotransition metal complexes, from synthesis to catalysis or to the study of fundamental reaction mechanisms. Currently they are interested in applying their expertise to the following research lines:
Cobalt-Catalyzed Intramolecular Cycloadditions of Alkenylidenecyclopropanes with Alkenes and Dienes.
Adv. Synth. Catal. 2024, 366, 762–767
2. C. Lorenzo-Aparicio, P. García-Álvarez, J. A. Cabeza, M. Gómez-Gallego and M. A. Sierra.
Nucleobase Stacking Sustained by Pt Pt Interactions
ChemistryEurope 2024, e202300065
3. T. V. Alves, E. Peris and I. Fernández.
A Deeper Insight into the Supramolecular Activation of Oxidative Addition Reactions Involving Pincer-Rhodium(I) Complexes
Chemphyschem 2024, 25, e202400022
4. I. Quirós, M. Martín, M. Gomez-Mendoza, M. J. Cabrera-Afonso, M. Liras, I. Fernandez, L. Novoa and M. Tortosa.
Isonitriles as Alkyl Radical Precursors in Visible Light Mediated Hydro- and Deuterodeamination Reactions.
Angew. Chem. Int. Ed. 2024, 63, e202317683
5. S. Aguado, P. Garcia-Alvarez, J. A. Cabeza, L. Casarrubios and M. A. Sierra.
A cross-metathesis approach for polymetallic [FeFe]-hydrogenase mimics.
Dalton Trans. 2024, 53, 3756-3764
6. B. Parra-Cadenas, I. Fernandez, F. Carrillo-Hermosilla, J. Garcia-Alvarez and D. Elorriaga.
Addition of allyl Grignard to nitriles in air and at room temperature: experimental and computational mechanistic insights in pH-switchable synthesis
Chem. Sci. 2024, 15, 5929-5937
7. S. Alberca, J. Romero-Parra, I. Fernandez, R. Fernandez, J. M. Lassaletta and D. Monge.
Enantioselective synthesis of alpha-aryl alpha-hydrazino phosphonates
Chem. Sci. 2024, 15, 7725-7731
8. M. Moreno-Latorre, M. C De la Torre, J. A. Cabeza, P. García-Álvarez, M. A. Sierra.
Attaching Metal-Complexes to β-Lactam Antibiotics: The Case of Penicillin and Cephalosporin
Inorg. Chem. 2024, 63, 12593-12603
9. M. Martínez de Sarasa Buchaca, F. de la Cruz-Martínez, J. Naranjo, A. M. Rodríguez, M. C. de la Torre, J. A. Castro-Osma, M. A. Sierra and A. Lara-Sánchez.
Design of New Bis(1,2,3-triazol-1-yl)methane-Based Nitrogen Ligands: Synthesis and Coordination Chemistry.
Chem. Eur. J. 2024, e202304291.
10. J. A. Cabeza, M. A. Esteruelas, I. Fernández, S. Izquierdo and E. Oñate.
A Lead-μ2‑Tetrylide Complex with Osmium(IV) Terminal Components
Inorg. Chem. 2024, 63, 15563-15567
11. M. Navarro, S. Sobrino, I. Fernández, A. Lara-Sánchez, A. Garcés and L. F. Sánchez-Barba.
Exploring enantiopure zinc-scorpionates as catalysts for the preparation of polylactides, cyclic carbonates and polycarbonates.
Dalton Trans. 2024, 53, 13933-13949
12. C. Lázaro-Milla, E. da Concepción, I. Fernández, J. L. Mascareñas and F. López.
Cobalt-Catalyzed (3 + 2) Cycloaddition of Cyclopropene-Tethered Alkynes: Versatile Access to Bicyclic Cyclopentadienyl Systems and Their CpM Complexes
ACS. Catal. 2024, 11574-11583
13. D. Lledó, G. Grindlay, H. Q. N. Gunaratne, A. de Cozar, A. Sirvent and J. M. Sansano.
A ciprofloxacin derived task specific ionic liquid as a highly selective extractant of thorium versus uranium
J. Mater. Chem. A, 2024, 12, 31557-31569
1. A. M. Álvarez-Constantino, A. Álvarez-Pérez, J. A. Varela, G. Sciortino, G. Ujaque and C. Saá
Chemoselective Ru-Catalyzed Oxidative Lactamization vs Hydroamination of Alkynylamines: Insights from Experimental and Density Functional Theory Studies
J. Org. Chem. 2023, 88, 1185−1193
2. P. Rodríguez-Salamanca, G. de Gonzalo, J. A. Carmona, J. López-Serrano, J. Iglesias-Sigüenza, R. Fernández, J. M. Lassaletta and V. Hornillos
Biocatalytic Atroposelective Synthesis of Axially Chiral N‑Arylindoles via Dynamic Kinetic Resolution
ACS Catal. 2023, 13, 659−664
3. G. Merino, M. Sola, I. Fernandez, C. Foroutan-Nejad, P. Lazzeretti, G. Frenking, H. L. Anderson, D. Sundholm, F. P. Cossio, M. A. Petrukhina, J. S. Wu, J. I. Wu and A. Restrepo,
Aromaticity: Quo Vadis
Chem. Sci. 2023, 14, 5569-5576
4. C. Lorenzo-Aparicio, S. Moreno-Blázquez, M. Oliván, M. A. Esteruelas, M. Gómez Gallego, P. García-Álvarez, J. A. Cabeza, and M. A. Sierra
Synthesis, Structure, and Photophysical Properties of Platinum(II) (N,C,N′) Pincer Complexes Derived from Purine Nucleobases
Inorg. Chem. 2023, 62, 8232-8248
5. M. Navarro, D. González-Lizana, L. F. Sánchez-Barba, A. Garcés, I. Fernández, A. Lara-Sánchez and A. M. Rodríguez
Development of Heterobimetallic Al/Mg Complexes for the Very Rapid Ring-Opening Polymerization of Lactides
Inorg. Chem. 2023, 62, 14833-14837
6. R. Hidalgo-León, N. Alberro, F. P. Cossío, J. M. Sansano, M. G. Retamosa
Remote Asymmetric Bisvinylogous [4+2] Cycloaddition Reaction to Synthesize Spirocyclic Frameworks
Adv. Synth. Catal. 2023, 365, 3253–3259
7. E. Da Concepción, C. Lázaro-Milla, I. Fernández, J. L. Mascareñas and F. López
Cobalt(I)-Catalyzed (3 + 2 + 2) Cycloaddition between Alkylidenecyclopropanes, Alkynes, and Alkenes
Org. Lett. 2023, 25, 8372−8376
1. D. Elorriaga, B. Parra-Cadenas, A. Antiñolo, F. Carrillo-Hermosilla, J. García-Álvarez
Combination of air/moisture/ambient temperature compatible organolithium chemistry with sustainable solvents: selective and efficient synthesis of guanidines and amidines
Green Chem., 2022, 24, 800-812
2. J. A. Cabeza, P. García-Álvarez, M. Gómez-Gallego and M. A. Sierra
Advances in the synthesis and reactivity of group 6 metal allenyls
Adv. Organomet. Chem., 2022, 77, 331-365
3. D. Elorriaga, F. Carrillo-Hermosilla, B. Parra-Cadenas, A. Antiñolo and J. García-Álvarez
Aerobic/Room-Temperature-Compatible s-Block Organometallic Chemistry in Neat Conditions: A Missing Synthetic Tool for the Selective Conversion of Nitriles into Asymmetric Alcohols
ChemSusChem, 2022, 15, e202201348
4. P. Rios, S. Conejero, I. Fernández
Bonding Situation of sigma-E-H Complexes in Transition Metal and Main Group Compounds
Chem. Eur. J., 2022, 28, e202201348
5. H. Corona, M. Pérez-Jiménez, F. de la Cruz.Martínez, I. Fernández, J, Campos
Divergent CO2 Activation by Tunning the Lewis Acid in Iron-Based Bimetallic Systems
Angew. Chem. Int., 2022, 61, e202207581
6. R. W. Adams, R. O. John, D. Blazina, B. Eguillor, M. C. R. Cockett, J. P. Dunne, J. López-Serrano, S. B. Duckett,
Contrasting Photochemical and Thermal Catalysis by Ruthenium Arsine Compl4exes Revealed by Parahydrogen Enhanced NMR Spectroscopy
Eur. J. Inorg. Chem., 2022, e202100991
7. S. Learte-Aymamí, P. Martin-Malpartida, L. Roldán-Martín, G. Sciortino, J. R. Couceiro, J-D. Maréchal, M. J. Macias, J. L. Mascareñas, M. E. Vázquez.
Controlling oncogenic KRAS signaling pathways with a Palladium-responsive peptide
Commun. Chem., 2022, 5, 75
8. J. Gómez-González, L. Martínez-Castro, J. Tolosa-Barrilero, A. Alcalde-Ordoñez, S. Learte-Aymamí, J. L. Mascareñas, J. C. García-Martínez, J. Martínez-Costas, J-D. Maréchal, M. Vázquez López, M. E. Vázquez.
Selective recognition of A/T-rich DNA 3-way junctions with a three-fold symmetric tripeptide
Chem. Commun., 2022, 58, 7769-7772
9. M. Agirre, T. Bello, J. Zhou, M. de Gracia Retamosa, F. P. Cossío
Synthesis of Bicyclic Hemiacetals Catalyzed by Unnatural Densely Substituted γ‑Dipeptides
J. Org. Chem., 2022, 87, 14819-14824
10. C. J. Laglera-Gándara, P. Rios, F. J. Fernández de Córdova, M. Barturen, I. Fernández, S.Conejero
σ‑GeH and Germyl Cationic Pt(II) Complexes
Inorg. Chem., 2022, 61, 20848-20859
1. L. C. Tolley, I. Fernández, D. I. Bezuidenhout, G. Guisado-Barrios
Catalytic conversion of alkynes to α-vinyl sulfides mediated by carbene-linker-carbene (CXC) rhodium and iridium complexes
Catal. Sci. Technol., 2021, 11, 516-523
2. P. Rios, R. Martín de la Calle, P. Vidossich, F. J. Fernández de Córdova, A. Lledós, S. Conejero
Reversible carbon–boron bond formation at platinum centers through s-BH complexes
Chem. Sci., 2021, 12, 1647-1655
3. P. Rios, J. Borge, F. J. Fernández de Córdova, G. Sciortino, A. Lledós, A. Rodríguez
Ambiphilic boryl groups in a neutral Ni(II) complex: a new activation mode of H2
Chem. Sci., 2021, 12, 2540-2548
4. A. Arauzo, J. A. Cabeza, I. Fernández, P. García-Álvarez, I. García-Rubio, C. J. Laglera-Gándara
Reactions of late first-row transition metal (Fe–Zn) dichlorides with a PGeP pincer germylene
Chem. Eur. J, 2021, 27, 4985-4992
5. F. León, A. Comas-Vives, E. Álvarez, A. Pizzano
A combined experimental and computational study to decipher complexity in the asymmetric hydrogenation of imines with Ru catalysts bearing atropisomerizable ligands.
Catal. Sci. Tech, 2021, https://doi.org/10.1039/D0CY02390F
6. J. C. Babón, M. A. Esteruelas, I. Fernández, A. M. López, E. Oñate
Assembly of a Dihydrideborate and Two Aryl Nitriles to Form a C,N,N′-Pincer Ligand Coordinated to Osmium
Organometallics, 2021, 40, 635-642.
7. M. L. Buil, A. Collado, M. A. Esteruelas, M. G. Gallego, S. Izquierdo, A. I. Nicasio, E. Oñate, M. A. Sierra
Preparation and Degradation of Rhodium and Iridium Diolefin Catalysts for the Acceptorless and Base-Free Dehydrogenation of Secondary Alcohols
Organometallics, 2021, 40, 989-1003.
8. E. Da Concepción, I. Fernández, J. L. Mascareñas, F. López
Highly Enantioselective Cobalt-Catalyzed (3+2) Cycloadditions of Alkynylidenecyclopropanes
Angew. Chem. Int Ed., , 2021, 60, 8182-8188.
9. N. Hidalgo, C. Romero-Pérez, C. Maya, I. Fernández, J. Campos
Reactivity of [Pt(PtBu3)2] with Zinc(I/II) Compounds: Bimetallic Adducts, Zn−Zn Bond Cleavage, and Cooperative Reactivity
Organometallics, 2021, 40, 1113-1119.
10. D. Elorriaga, F. de la Cruz-Martínez, M. J. Rodríguez-Álvarez, A. Lara-Sanchez, J. A. Castro-Osma, J. García-Álvarez
Fast Addition of s-Block Organometallic Reagents to CO2-derived Cyclic Carbonates at Room Temperature, Under Air, and in 2-Methyltetrahydrofuran
ChemSusChem, 2021, 14 2084-2092.
11. M. Navarro, J. Miranda-Pizarro, J. J. Moreno, C. Navarro-Gilabert,I. Fernández and J. Campos
A dicoordinate gold(I)–ethylene complex
Chem. Commun., 2021, 57, 9280-9283.
12. P. Ríos,F. J. Fernández-de-Córdova,J. Borge,N. Curado, A. Lledós and S. Conejero
Ligand Effects in Carbon-Boron Coupling Processes Mediated by σ-BH Platinum Complexes
Eur. J. Inorg. Chem., 2021, 57, 3528-3539.
13. M. L. Buil, J. A. Cabeza, M. A. Esteruelas, S. Izquierdo, C. J. Laglera-Gándara, A. I. Nicasio and E. Oñate
Alternative Conceptual Approach to the Design of Bifunctional Catalysts: An Osmium Germylene System for the Dehydrogenation of Formic Acid
Inorg. Chem., 2021, 60, 16860-16870.
14. J. A. Cabeza, I. Fernández, P. García-Álvarez, R. García-Soriano, C. J. Laglera-Gándara and R. Toral
Stannylenes based on pyrrole-phosphane and dipyrromethane-diphosphane scaffolds: syntheses and behavior as precursors to PSnP pincer palladium(II), palladium(0) and gold(I) complexes
Dalton. Trans., 2021, 50, 16122-16132.
15. S. Poyraz, S. Belveren, S. Aydınoğlu, M. Ulger, A. de Cózar, M. G. Retamosa, J. M. Sansanoand H. A. Döndaş
Biological properties and conformational studies of amphiphilic Pd(II) and Ni(II) complexes bearing functionalized aroylaminocarbo-N-thioylpyrrolinate units
Beilstein J. Org. Chem. 2021, 17, 2812–2821.
16. O. Bernardo, K. Yamamoto, I. Fernández, L. A. López
Reactivity of Stabilized Vinyldiazo Compounds toward Alkenyl- And Alkynylsilanes under Gold Catalysis: Regio- and Stereoselective Synthesis of Skipped Dienes and Enynes
Org. Lett. 2021, 23, 4452–4456.
1. M. Valencia, A. D. Merinero, C. Lorenzo-Aparicio, M. Gómez-Gallego, M. A. Sierra, B. Eguillor, M. A. Esteruelas, Oliván, E. Oñate
Osmium-Promoted sigma-Bond Activation Reactions on Nucleosides
Organometallics 2020, 39, 312-323
2. A. Granados, A. Shafir, A. Arrieta, F. P. Cossío and A. Vallribera
Stepwise Mechanism for the Bromination of Arenes by a Hypervalent Iodine Reagent
J. Org. Chem. 2020, 85, 2142-2150.
3. E. García-Minguens, V. Selva, O. Larrañaga, C. Nájera, J. M. Sansano, A de Cózar
Nitroprolinates as Nucleophiles in Michael-type Additions and Acylations. Synthesis of Enantiomerically Enriched Fused Amino-pyrrolidino-[1,2-a]pyrazinones and -diketopiperazines
Chem. Cat. Chem. 2020, 12, 2014-2021
4. S. Ruiz-Botella, P. Vidossich, G. Ujaque and E. Peris
A resorcinarene-based tetrabenzoimidazolylidene complex of rhodium
Dalton Trans., 2020, 49, 3181–3186
5. A. Romero-Arenas, V. Hornillos, J. Iglesias Siguenza, R. Fernández, J. López-Serrano, A. Ros, J. M. Lassaletta
Ir-Catalyzed Atroposelective Desymmetrization of Heterobiaryls: Hydroarylation of Vinyl Ethers and Bicycloalkenes
J. Am. Chem. Soc. 2020, 142, 2628–2639
6. R. Nelson, M. Calvelo, R. García-Fandiño, A. Lledós, G. Ujaque, J. L. Mascareñas and F. López
Skeletal diversity in Pt- and Au-catalyzed annulations of allenedienes: dissecting unconventional mechanistic pathways
Chem. Sci. 2020, 11, 4209–4220
7. C. Moreno-Cabrerizo, A. Ortega-Martínez, M. A. Esteruelas, A. M. López, C. Nájera and J. M. Sansano
Deacylative Alkylation vs. Photoredox Catalysis in the Synthesis of 3,3′-Bioxindoles
Eur. J. Org. Chem. 2020, 3101–3109
8. M. Navarro, L. F. Sánchez-Barba, A. Garcés, J. Fernández-Baeza, Israel Fernández, A. Lara-Sánchez and A. M. Rodríguez
Bimetallic scorpionate-based helical organoaluminum complexes for efficient carbon dioxide fixation into a variety of cyclic carbonates
Catal. Sci. Technol., 2020, 10, 3265-3278
9. E. García-Mingüens, V. Selva, O. Larrañaga, C. Nájera, J. M. Sansano and A. de Cózar.
Nitroprolinates as Nucleophiles in Michael-type Additions and Acylations. Synthesis of Enantiomerically Enriched Fused Amino-pyrrolidino-[1,2-a]pyrazinones and -diketopiperazines
ChemCatChem 2020, 12, 2014–2021
10. J. C. Babón, M. A. Esteruelas, I. Fernández, A. M. López, E. Oñate.
Dihydroboration of Alkyl Nitriles Catalyzed by an Osmium-Polyhydride: Scope, Kinetics, and Mechanism
Organometallics 2020, 39, 3864–3872
11. M. Chehrouri, C. Moreno-Cabrerizo, A. A. Othman, I. Chabour, M. Ferrandiz-Saperas, I. Sempere, H. A. Dondas, M. D. Retamosa, J. M. Sasnsano.
4-Amino-1,2,4-triazoles-3-thiones and 1,3,4-oxadiazoles-2-thiones.palladium(II) recoverable complexes as catalysts in the sustainable Suzuki-Miyaura cross-coupling reaction
J. Organomet. Chem. 2020, 923, 121353
1. A. E. Roa, V. Salazar, D. Mendoza-Espinosa, M. Paneque, A Rodríguez-Diéguez, A. M. Rodríguez, J. Tejeda, J. A. Castro-Osma, A. Otero, A. Lara-Sánchez
Study of the Coordination Modes of Hybrid NNCp Cyclopentadienyl/Scorpionate Ligands in Ir Compounds
Inorg. Chem. 2019, 58, 900-908.
2. A. Couce-Ríos, A. Lledós, I. Fernández, G. Ujaque,
Origin of the Anti-Markovnikov Hydroamination of Alkenes Catalyzed by L–Au(I) Complexes: Coordination Mode Determines Regioselectivity
ACS Catal. 2019, 9, 848-858.
3. F. León, J. Francos, J. López-Serrano, S. E. García-Garrido, V. Cadierno and A. Pizzano
Double asymmetric hydrogenation of conjugated dienes: a self-breeding chirality route for C2 symmetric 1,4-diols
Chem. Commun., 2019, 54, 786-789.
4. A. Antiñolo, M. A., Esteruelas, C. García-Yebra, J. Martín, E. Oñate and A. Ramos
Reactions of an Osmium(IV)-Hydroxo Complex with Amino-Boranes:
Formation of Boroxide Derivatives
Organometallics., 2019, 38, 310-318. Front Cover
5. L. Álvarez-Rodríguez, J. A. Cabeza, P. García-Álvarez, M. Gómez-Gallego, L. González-Álvarez, A. D. Merinero and M. A. Sierra
Reversible Carbene Insertion into a Ge-N Bond and Insights into CO and Carbene Substitution Reactions Involving
Amidinatogermylenes and Fischer Carbene Complexes
Chem. Eur. J., 2019, 25, 1588-1594.
6. J. A. Cabeza, P. García-Álvarez, M. Gómez-Gallego, L. González-Álvarez, A. D. Merinero and M. A. Sierra
Unexpected Zwitterionic Allenyls from Silylenes and a Fischer Alkynylcarbene: A Remarkable Silylene-Promoted Rearrangement
Chem. Eur. J., 2019, 25, 2222-2225.
7. M. A., Esteruelas, I. Fernández, C. García-Yebra, J. Martín and E. Oñate
Cycloosmathioborane Compounds: Other Manifestations of the Hückel Aromaticity
Inorg. Chem., 2019, 58, 2265-2269.
8. M. A., Esteruelas, I. Fernández, A. Martínez, M. Oliván, E. Oñate and A. Vélez
Iridium-Promoted B-B Bond Activation: Preparation and X-ray Diffraction Analysis of a mer–Tris(boryl) Complex
Inorg. Chem., 2019, 58, 4712-4717.
9. J. C. Babón, M. A., Esteruelas, I. Fernández, A. M. López and E. Oñate
Reduction of Benzonitriles via Osmium-Azavinylidene Intermediates Bearing Nucleophilic and Electrophilic Centers
Inorg. Chem., 2019, 58, 8673-8684.
10. J. A. Cabeza, P. García-Álvarez, M. Gómez-Gallego, L. González-Álvarez, A. D. Merinero and M. A. Sierra
Two Types of sigma-Allenyl Complexes from Reactions of Silylenes and Germylenes with Chromium Fischer Alkynyl(alkoxy)carbenes
Chem. Eur. J., 2019, 25, 8635-8642.
11. H. A. Dondas, M. G. Retamosa, J. M. Sansano
Recent Development in Palladium-Catalyzed Domino Reactions: Acess to Materials and Biologically Important Carbo- and Heterocycles
Organometallics., 2019, 38, 1828-1867.
12. A. Álvarez-Pérez, M. A. Esteruelas, S. Izquierdo, J. Varela, C. Saá
Ruthenium-Catalyzed Oxidative Amidation of Alkynes to Amides
Org. Lett., 2019, 21, 5346-5350.
13. S. Caleffi, O. Larranaga, M. Ferrandiz-Saperas, P. R. R. Costa, C. Najera, A. de Cózar, F. P. Cossío and J. M. Sansano.
Switching Diastereoselectivity in Catalytic Enantioselective (3+2) Cycloadditions of Azomethine Ylides Promoted by Metal Salts and Privileged Segphos-Derived Ligands
J. Org. Chem. 2019, 84, 10593-10605.
14. A. Granados, I. Rivilla, F. P. Cossío and A. Vallribera.
Lanthanum-Catalyzed Enantioselective Trifluoromethylation by Using an Electrophilic Hypervalent Iodine Reagent
Chem. Eur. J. 2019, 25, 8214-8218.
15. S. Belveren, O. Larrañaga, S. Poyraz, H. A. Dondas, M. Ulger, E. Sahin, M. Ferrándiz-Saperas, J. M. Sansano, M. de G. Retamosa and A. de Cózar.
From bioactive Pyrrolidino[3,4-c]pyrrolidines to more bioactive Pyrrolidino[3,4-b]pyrrolidines via ring-opening/ring closing promoted by Sodium Methoxide
Synthesis 2019, 51, 1565-1577.
16. J. A. Cabeza, I. Fernández, J. M. Fernández-Colinas, P. García-Álvarez and C. J. Laglera-Gándara.
A germylene supported by two 2-pyrrolylphosphane groups as precursor to PGeP pincer square-planar Group 10 metal(II) and T-shaped gold(I) complexes.
Chem. Eur. J. 2019, 25, 12423-12430.
17. J. A. Cabeza, I. Fernández, P. García-Álvarez and C. J. Laglera-Gándara.
A dipyrromethane-based diphosphane–germylene as precursor to tetrahedral copper(I) and T-shaped silver(I) and gold(I) PGeP pincer complexes.
Dalton Trans., 2019, 48, 13273-13280.
18. P. Ríos, H. Fouilloux, J. Díez, P. Vidossich, A. Lledós and S. Conejero.
σ-Silane Platinum(II) Complexes as Intermediates in C-Si Bond-Coupling Processes
Chem. Eur. J. Trans., 2019, 25, 11346-11355.
1. P. Ríos, M. Roselló-Merino, O. Rivada-Wheelaghan, J. Borge, J. López-Serrano, S. Conejero
Selective Catalytic Synthesis of Amino-silanes at Part-Per Million Catalyst Loadings
Chem. Commun., 2018, 54, 619-622
2. M. L. Buil, M. A Esteruelas, M. P. Gay, M. Gómez Gallego, A. Nicasio, E.Oñate, A. Santiago, M. A. Sierra
Osmium Catalysts for Acceptorless and Base-Free Dehydrogenation of Alcohols and Amines: Unusual Coordination Modes of a BPI Anion
Organometallics, 2018, 37, 603-607
3. P. Ríos, H. Fouilloux, P. Vidossich, J. Díez, A. Lledós, S. Conejero
Isolation of a Cationic Platinum(II) sigma-Silane Complex
Angew. Chem. Int. Ed., 2018, 57, 3217-3221
4. V. Hornillos, J. A. Carmona, A. Ros, J. Iglesias-Sigüenza, J. López-Serrano, R. Fernández, J. M. Lassaletta
Dynamic Kinetic Resolution of Heterobiaryl Ketones by Zinc-Catalyzed Asymmetric Hydrosilylation
Angew. Chem. Int. Ed., 2018, 57, 3777-3781
5. J. C. Babón, M. A. Esteruelas, I. Fernández, A. M. López, E. Oñate
Evidence for a Bis(Elongated σ)-Dihydrideborate Coordinated to Osmiun
Inorg. Chem., 2018, 57, 4482-4491
6. E. de Julián, E. Menéndez-Pedregal, M. Claros, M. Vaquero, J. Díez, E. Lastra, P. Gamasa, A. Pizzano
Practical synthesis of enantiopure benzylamines by catalytic hydrogenation or transfer hydrogenation reactions in isopropanol using a Ru-pybox catalyst
Org. Chem. Frontiers, 2018, 5, 841-849
7. A. Cayuelas, O. Larrañaga, V. Selva, C. Nájera,T. Akiyama, J. M. Sansano, A. de Cózar, J. I. Miranda, F. P. Cossío
Cooperative Catalysis with Coupled Chiral Induction in 1,3-Dipolar Cycloadditions of Azomethine Ylides
Chem. Eur. J. 2018, 24, 8092-8097
8. J. C. Babón, M. A. Esteruelas, I. Fernández, A. M. López, E. Oñate
Redox-Assisted Osmium-Promoted C−C Bond Activation of Alkylnitriles
Organometallics 2018, 37, 2014−2017
9. J. Francos, J. Borge, S. Conejero, V. Cadierno
Platinum Complexes with a Phosphino-Oxime/Oximate Ligand
Eur. J. Inorg. Chem. 2018, 3176−3186
10. A. Garcés, L. F. Sánchez-Barba, J. Fernández-Baeza, A. Otero, I. Fernández, A. Lara-Sánchez, A. M. Rodríguez
Organo Aliminium and Zinc Acetamidinates: Preparation, Coordination Ability and Ring Opening Polymerization Processes of Cyclic Esters
Inorg. Chem. 2018, 57, 12132−12142
1. M. Frutos, M. A. Ortuño, A. Lledós, A. Viso, R. Fernández de la Pradilla, M. C. De la Torre, M. A. Sierra, H. Gornitzka, C. Hemmert
Desulfinylation of Ag(I) Sulfinyl Mesoionic Carbenes: Preparation of C-Unsubstituted Au(I)–1,2,3-Triazole Carbene Complexes
Org. Lett., 2017, 19, 822–825
2. L. Álvarez-Rodríguez, J. A. Cabeza, P. García-Álvarez, M. Gómez-Gallego, A. D. Merinero, M. A. Sierra
First Insertions of Carbene Ligands into Ge-N and Si-N Bonds
Chem. Eur. J., 2017, 23, 4287–4291
3. S. Ruiz-Botella, P. Vidossich, G. Ujaque, E. Peris, P. Beer
Tripodal halogen bonding iodo-azolium receptors for anion recognition
RSC Advances, 2017, 7, 11253-11258
4. Leon, F.; González-Liste, P.; García-Garrido, S. E.; Arribas, I.; Rubio, M.; Cadierno, V.; Pizano, A.
Broad Scope Synthesis of Ester Precursors of Nonfunctionalized Chiral Alcohols Based on the Asymmetric Hydrogenation of α,β-Dialkyl , α,β-Diaryl , and α Alkyl-β-aryl-vinyl Esters
J. Org. Chem. 2017, 82, 5852−5867
5. Esteruelas, M. A.; Fernández, I.; García-Yebra, C.; Martín, J.; Oñate, E.
Elongated σ-Borane versus σ-Borane in Pincer-POP-Osmium Complexes
Organometallics 2017, 36, 2298−2387
6. Selva, V.; Larrañaga, O.; Castelló, L. M.; Nájera, C.; Sansano, J. M.; De Cózar, A.
Diastereoselective [3 + 2] vs [4 + 2] Cycloadditions of Nitroprolinates with α,β-Unsaturated Aldehydes and Electrophilic Alkenes: An Example of Total Periselectivity
J. Org. Chem. 2017, 82, 6298−6312
7. Lahosa, A.; Soler, T.; Arrieta, A. ; Cossío, F. P.; Foubelo, F.; Yus, M.
Stereoselective Coupling of N-tert-Butanesulfinyl aldimines and β-Ketoacids: Access to β-Aminoketones
J. Org. Chem. 2017, 82, 7481−7491
8. I. Chabour, L. M. Castelló, J. Mancebo-Aracil, M. Martín-Rodríguez, M. de G. Retamosa, C. Nájera and J. M. Sansano
Dual Chiral Silver Catalyst in the Synthetic Approach to the core of Hepatitis C Virus inhibitor GSK 625433 using Enantioselective 1,3-dipola Cycloaddition of Azomethine Ylides and Electrophilic Alkenes
Tetrahedron: Assymmetry 2017, 28, 1423-1429
1. A. de Cózar, O. Larrañaga, F. M. Bickelhaupt, E. San Sebastián, E. Ortega-Carrasco, J.-D. Maréchal, A. Lledós, F. P. Cossío
New Insights into the Reactivity of Cisplatin with Free and Restrained Nucleophiles: Microsolvation Effects and Base Selectivity in Cisplatin-DNA Interactions
ChemPhysChem 2016, 17, 3932–3947
2. S. Izquierdo, S. Essafi, I. del Rosal, P. Vidossich, R. Pleixats, A. Vallribera, G. Ujaque, A. Lledós, A. Shafir
Acid Activation in Phenyliodine Dicarboxylates: Direct Observation, Structures, and Implications
J. Am. Chem. Soc. 2016, 138, 12747-12750
3. A. Cayuelas, O. Larrañaga, C. Nájera, J. M. Sansano, A. de Cózar, F. P. Cossío
Taniaphos·AgF-catalyzed enantioselective 1,3-dipolar cycloaddition of stabilized azomethine ylides derived from 2,2-dimethoxyacetaldehyde
Tetrahedron 2016, 72, 6043-6051.
4. M. A. Esteruelas, P. Nolis, M. Oliván, E. Oñate, A. Vallribera, A. Vélez
Ammonia-Borane Dehydrogenation Promoted by a Pincer-Square-Planar Rhodium(I)-Monohydride: A Stepwise Hydrogen Transfer from the Substrate to the Catalyst
Inorg. Chem. 2016, 55, 7176-7181
5. C. Cristóbal, L. L. Santos, R. Gutiérrez-González, E. Álvarez, M. Paneque, M. L. Poveda
Allylic C–H Activation of Olefins by a TpMe2IrIII Compound
Eur. J. Inorg. Chem. 2016, 2534-2542
6. M. Roselló-Merino, R. J. Rama, J. Díez, S. Conejero
Catalytic dehydrocoupling of amine-boranes and amines into diaminoboranes: isolation of a Pt(II), Shimoi-type, η1-BH complex
Chem. Commun. 2016, 52, 8389-8392
7. A. Cayuelas, R. Ortiz, C. Nájera, J. M. Sansano, O. Larrañaga, A. de Cózar, F. P. Cossío
Enantioselective Synthesis of Polysubstituted Spiro-nitroprolinates Mediated by a (R,R)‑Me-DuPhos·AgF-Catalyzed 1,3-Dipolar Cycloaddition
Org. Lett. 2016, 18, 2926-2929
8. C. Valderas, L. Casarrubios, A. Lledós, M. A. Ortuño, M. C. de la Torre, M. A. Sierra
Silver(I)-Catalyzed Addition of Phenols to Alkyne Cobalt Cluster Stabilized Carbocations
Chem. Eur. J. 2016, 22, 9015-9023
9. P. J. González-Liste, F. León, I. Arribas, M. Rubio, S. E. García-Garrido, V. Cadierno, A. Pizzano
Highly Stereoselective Synthesis and Hydrogenation of (Z)‑1-Alkyl-2-arylvinyl Acetates: a Wide Scope Procedure for the Preparation of Chiral Homobenzylic Esters
ACS Catal. 2016, 6, 3056-3060
10. M. L. Buil, J. J. F. Cardo, M. A. Esteruelas, I. Fernández, E. Oñate
An Entry to Stable Mixed Phosphine−Osmium−NHC Polyhydrides
Inorg. Chem. 2016, 55, 5062-5070
11. P. Sabater, F. Zapata, A. Caballero, I. Fernández, C. Ramirez de Arellano, P. Molina
2,4,5-Trimethylimidazolium Scaffold for Anion Recognition Receptors Acting Through Charge-Assisted Aliphatic and Aromatic C−H Interactions
J. Org. Chem. 2016, 81, 3790-3798
12. G. M. Chu, A. Guerrero-Martínez, C. Ramírez de Arellano, I. Fernández, M. A. Sierra
Remote Control by π‑Conjugation of the Emissive Properties of Fischer Carbene-BODIPY Dyads
Inorg. Chem. 2016, 55, 2737-2747
13. G. M. Chu, I. Fernández, A. Guerrero-Martínez, C. Ramírez de Arellano, M. A. Sierra
Fluorescence Quenching in BODIPYs Having Ir- and Rh-Tethered Complexes
Eur. J. Inorg. Chem. 2016, 844-852
14. J. A. Castro-Osma, A. Lara-Sánchez, A. Otero, A. M. Rodríguez, M. C. de la Torre, M. A. Sierra
An Efficient and Tunable Route to Bis(1,2,3-triazol-1-yl)methane-Based Nitrogen Compounds
Eur. J. Org. Chem. 2016, 682-687
15. J. Francos, P. J. González-Liste, L. Menéndez-Rodríguez, P. Crochet, V. Cadierno, J. Borge, A. Antiñolo, R. Fernández-Galán, F. Carrillo-Hermosilla
Half-Sandwich Guanidinate–Osmium(II) Complexes: Synthesis and Application in the Selective Dehydration of Aldoximes
Eur. J. Inorg. Chem. 2016, 393-402
16. N. Casanova, M. A. Esteruelas, M. Gulías, C. Larramona, J. L. Mascareñas, E. Oñate
Amide-Directed Formation of Five-Coordinate Osmium-Alkylidenes from Alkynes
Organometallics 2016, 35, 91-99
17. Ruiz-Botella, P. Vidossich, G. Ujaque, E. Peris
Rim, Side Arms and Cavity: Three Sites for the Recognition of Anions by Tetraazolium Resorcinarene Cavitands
Chem. Eur. J. 2016, 22, 15800-15806.
18. A. Sierra, A. D. Merinero, E. A. Giner, Mar Gómez-Gallego, C. Ramírez de Arellano
An Entry to Mixed NHC–Fischer Carbene Complexes and Zwitterionic Group 6 Metal Alkenyls
Chem. Eur. J. 2016, 22, 13521-13531
19. Rull, J. J. Jara, R. M. Sebastián, A. Vallribera, C. Nájera, J.-P. Majoral, A.-M. Caminade,
Recoverable Dendritic Phase-Transfer Catalysts that Contain (+)-Cinchonine-Derived Ammonium Salts
ChemCatChem. 2016, 8, 2049-2056
20. P. Ríos, J. Díez, J. López-Serrano, A. Rodríguez, S. Conejero
Cationic Platinum(II) σ-SiH Complexes in Carbon Dioxide Hydrosilation
Chem. Eur. J. 2016, 22, 16791-16795
1. J. Mancebo-Aracil, C. Nájera, L. M. Castelló, J. M. Sansano, O. Larrañaga, A. de Cózar, F. P. Cossío
Regio and diastereoselective multicomponent 1,3-dipolar cycloadditions between prolinate hydrochlorides, aldehydes and dipolarophiles for the direct synthesis of pyrrolizidines
Tetrahedron 2015, 71, 9645-9661
2. L. Casarrubios, M. A. Esteruelas, C. Larramona, J. G. Muntaner, E. Oñate, M. A. Sierra
2-Azetidinones as Precursors of Pincer Ligands: Preparation, Structure, and Spectroscopic Properties of CC′N-Osmium Complexes
Inorg. Chem. 2015, 54, 10998-11006
3. L. Casarrubios, M. A. Esteruelas, C. Larramona, A. Lledós, J. G. Muntaner, E. Oñate, M. A. Ortuño, M. A. Sierra
Mechanistic Insight into the Facilitation of β-Lactam Fragmentation through Metal Assistance: Mechanistic Insight
Chem. Eur. J. 2015, 21, 16781-16785
4. A. Álvarez-Pérez, C. González-Rodríguez, C. García-Yebra, J. A. Varela, E. Oñate, M. A. Esteruelas, C. Saá
Catalytic Cyclization of o-Alkynyl Phenethylamines via Osmacyclopropene Intermediates: Direct Access to Dopaminergic 3-Benzazepines
Angew. Chem. Int. Ed. 2015, 54, 13357-13361
5. P. R. R. Costa, J. M. Sansano, U. Cossío, J. C. F. Barcellos, A. G. Dias, C. Nájera, A. Arrieta, A. de Cózar, F. P. Cossío
Synthesis of Chromen[4,3-b]pyrrolidines by Intramolecular 1,3-Dipolar Cycloadditions of Azomethine Ylides: An Experimental and Computational Assessment of the Origin of Stereocontrol
Eur. J. Org. Chem. 2015, 4689-4698
6. T. Bolaño, M. A. Esteruelas, M. P. Gay, E. Oñate, I. M. Pastor, M. Yus
An Acyl-NHC Osmium Cooperative System: Coordination of Small Molecules and Heterolytic B−H and O−H Bond Activation
Organometallics 2015, 34, 3902-3908
7. L. Menéndez-Rodríguez, E. Tomás-Mendivil, J. Francos, P. Crochet, V. Cadierno, A. Antiñolo, R. Fernández-Galán, F. Carrillo-Hermosilla
Reactivity of the Dimer [{RuCl(μ-Cl)(η3:η3‑C10H16)}2] (C10H16 = 2,7-Dimethylocta-2,6-diene-1,8-diyl) toward Guanidines: Access to Ruthenium(IV) and Ruthenium(II) Guanidinate Complexes
Organometallics 2015, 34, 2796-2809
8. L. Menéndez-Rodríguez, E. Tomás-Mendivil, J. Francos, C. Nájera, P. Crochet, V. Cadierno
Palladium complexes with a phosphino-oxime ligand: synthesis, structure and applications to the catalytic rearrangement and dehydration of aldoximes
Catal. Sci. Technol. 2015, 5, 3754-3761
9. B. Eguillor, M. A. Esteruelas, I. Fernández, M. Gómez-Gallego, A. Lledós, M. Martín-Ortiz, M. Oliván, E. Oñate, M. A. Sierra
Azole Assisted C−H Bond Activation Promoted by an Osmium-Polyhydride: Discerning between N and NH
Organometallics 2015, 34, 1898-1910
10. E. A. Giner, A. Santiago, M. Gómez-Gallego, C. Ramírez de Arellano, R. C. Poulten, M. K. Whittlesey, M. A. Sierra
Mono- and Bimetallic Zwitterionic Chromium(0) and Tungsten(0) Allenyls
Inorg. Chem. 2015, 54, 5450-5461
11. L. M. Castelló, C. Nájera, J. M. Sansano, O. Larrañaga, A. de Cózar, F. P. Cossío
Enantioselective synthesis of exo-4-Nitroprolinates from Nitroalkenes and Azomethyne Ylides Catalyzed by Chiral Phosphoramidite·Silver of Copper Complexes
Synthesis 2015, 47, 934-943
12. T. Bolaño, M. A. Esteruelas, I. Fernández, E. Oñate, A. Palacios, J.-Y. Tsai, C. Xia
Osmium(II)−Bis(dihydrogen) Complexes Containing Caryl,CNHC−Chelate Ligands: Preparation, Bonding Situation, and Acidity
Organometallics 2015, 34, 778−789
13. M. L. Buil, J. J. F. Cardo, M. A. Esteruelas, I. Fernández, E. Oñate
Hydroboration and Hydrogenation of an Osmium−Carbon Triple Bond: Osmium Chemistry of a Bis-σ-Borane
Organometallics 2015, 34, 547−550
14. A. E. Roa, J. Campos, M. Paneque, V. Salazar, A. Otero, A. Lara-Sánchez, A. M. Rodríguez, I. López-Solera, M. V. Gómez
Synthesis of new heteroscorpionate iridium(I) and iridium(III) complexes
Dalton Trans. 2015, 44, 6987-6998
15. G. Retamosa, A. de Cózar, M. Sánchez, J. I. Miranda, J. M. Sansano, L. M. Castelló, C. Nájera, A. I. Jiménez, F. J. Sayago, C. Cativiela F. P. Cossío
Remote Substituent Effects on the Stereoselectivity and Organocatalytic Activity of Densely Substituted Unnatural Proline Esters in Aldol Reactions
Eur. J. Org. Chem. 2015, 2503-2516
16. Menendez-Pedregal, M. Vaquero, E. Lastra, P. Gamasa, A. Pizzano,
Highly Enantioselective Hydrogenation of N-Aryl Imines Derived from Acetophenones by Using Ru-Pybox Complexes under Hydrogenation or Transfer Hydrogenation Conditions in Isopropanol
Chem. Eur. J. 2015, 21, 549-553.
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